Abstract

Traditional gunshot residue analysis is based on the detection of lead (Pb), barium (Ba) and antimony (Sb). CCI's recent development of a lead free centerfire primer for their Blazer® Lead Free ammunition presents a new challenge for forensic scientists since it does not contain lead, barium or antimony. Research presented here is the result of the analysis of this new primer by scanning electron microscopy/energy dispersive X-ray which involved analyzing CCI's lead free primer directly as well as the gunshot residue obtained by test firing a series of firearms using CCI's Blazer® Lead Free ammunition. Analysis of the residue from a fired primer determined that the only metal present was strontium; however, when the lead free ammunition is discharged in firearms previously fired using traditional primer ammunition, particles containing lead, barium and antimony were detected. These findings hold true for older firearms cleaned prior to testing as well as a “new” firearm that had only been test fired by the manufacturer.

References

1.
Lawrence
,
G. M.
, “
‘Lead-Free’ or ‘Clean-Fire’?
,” presented at the
Southwestern Association of Forensic Scientists Spring Meeting
,
South Padre Island, TX
, Spring
1993
.
2.
Bydal
,
B. A.
, “
Percussion Primer Mixes
,”
AFTE Journal
, Vol.
22
, No.
1
,
01
1990
, pp.
1
-
25
.
3.
Wallace
,
J. S.
, “
Chemical Aspects of Firearms Ammunition
,”
AFTE Journal
, Vol.
22
, No.
4
, Oct., 1990, pp.
364
-
389
.
4.
DeGaetano
,
D.
and
Siegel
,
J. A.
, “
Survey of Gunshot Residue Analysis in Forensic Science Laboratories
,”
Journal of Forensic Sciences
 0022-1198, Vol.
35
, No.
5
,
09
1990
, pp.
1087
-
1095
.
5.
Encyclopedia of Chemical Technology
, Vol.
13
,
R. E.
Kirk
and
D. F.
Othmer
, Eds.,
New York
,
The Interscience Encyclopedia, Inc.
,
1954
.
6.
Davis
,
T. L.
,
The Chemistry of Powder and Explosives
,
Angriff Press
,
California
,
1943
.
7.
The Merck Index
, 11th Edition, Ed.,
Budavari
,
S.
,
Merck & Co., Inc.
,
1989
.
8.
Andrasko
,
J.
, “
Identification of Burnt Matches by Scanning Electron Microscopy
,”
Journal of Forensic Sciences
 0022-1198, Vol.
23
, No.
4
,
10
1978
, pp.
637
-
642
.
9.
Glattstein
,
B.
,
Landau
,
E.
, and
Zeichner
,
A.
, “
Identification of Match Head Residues in Post-Explosion Debris
,”
Journal of Forensic Sciences
 0022-1198, Vol.
36
, No.
5
,
09
1991
, pp.
1360
-
1367
.
10.
Zeichner
,
A.
,
Levin
,
N.
, and
Springer
,
E.
, “
Gunshot Residue Particles Formed by Using Different Types of Ammunition in the Same Firearm
,”
Journal of Forensic Sciences
 0022-1198, Vol.
36
, No.
4
,
07
1991
, pp.
1020
-
1026
.
11.
Gunaratnam
,
L.
and
Himberg
,
K.
, “
The Identification of Gunshot Residue Particles from Lead-Free Sintox Ammunition
,”
Journal of Forensic Sciences
 0022-1198, Vol.
39
, No.
2
,
03
1994
, pp.
532
-
536
.
This content is only available via PDF.
You do not currently have access to this content.