The effects of substrate material, substrate surface roughness, and operating temperature on the wetting behavior of Sn–37Pb, Sn–3.5Ag, and Sn–9Zn eutectic solders on metallic substrates were investigated. Solder spreading kinetics was successfully represented by the exponential power law (EPL): . The EPL parameter has the significance of accelerating the kinetics of relaxation while the parameter represents the resistance to spreading process (spread resistance parameter). EPL parameters exhibited a decreasing trend with an increase in surface roughness. Estimated activation energies for solder spreading were found to be in between those reported for inert and highly reactive spreading systems.
Issue Section:
Research Papers
1.
Wu
, C. M. L.
, Yu
, D. Q.
, Law
, C. M. T.
, and Wang
, L.
, 2002, “The Properties of Sn-9Zn Lead-Free Solder Alloys Doped With Trace Rare Earth Elements
,” J. Electron. Mater.
0361-5235, 31
(9
), pp. 921
–927
.2.
Vianco
, P. T.
, and Frear
, D. R.
, 1993, “Issues in the Replacement of Lead-Bearing Solders
,” J. Mater.
0022-2453, 45
(7
), pp. 14
–19
.3.
Suganuma
, K.
, 2001, “Advances in Lead-Free Electronics Soldering
,” Curr. Opin. Solid State Mater. Sci.
1359-0286, 5
, pp. 55
–64
.4.
Manko
, H. H.
, 1992, Solders and Soldering
, 3rd ed., McGraw-Hill
, New York
, pp. 1
–153
.5.
Frear
, D. R.
, Jones
, W. B.
, and Kinsman
, K. R.
, 2002, Solder Mechanics—A State of the Art Assessment
, TMS
, Warrendale, PA
, pp. 1
–104
.6.
Kandlikar
, S. G.
, and Steinke
, M. E.
, 2002, “Contact Angles and Interface Behaviour During Rapid Evaporation of Liquid on a Heated Surface
,” Int. J. Heat Mass Transfer
0017-9310, 45
, pp. 3771
–3780
.7.
Martorano
, K. M.
, Martorano
, M. A.
, and Brandi
, S. D.
, 2004, “Effects of Solder Bath Temperature and Substrate Sheet Thickness on the Wetting Balance Curve
,” Engenharia Metalugica/USP, pp. 1
–14
.8.
Kang
, S. C.
, Kim
, C.
, Muncy
, J.
, Schmidt
, M.
, and Baldwin
, D.
, 2004, “Experimental Wetting Dynamics Study of Eutectic and Lead-Free Solders Varying Flux, Temperature and Surface Finish Metallization
,” 29th International IEEE/CPMT/SEMI Electronics Manufacturing Technology Symposium
, San Jose, CA, Jul. 14–16, pp. 56
–63
.9.
Peebles
, D. E.
, Peebles
, H. C.
, and Ohlhausen
, J. A.
, 1998, “Kinetics of the Isothermal Spreading of Tin on the Air-Passivated Copper Surface in the Absence of a Fluxing Agent
,” Colloids Surf., A
0927-7757, 144
, pp. 89
–114
.10.
Lopez
, V. H.
, and Kennedy
, A. R.
, 2006, “Flux-Assisted Wetting and Spreading of Al on Ti
,” J. Colloid Interface Sci.
0021-9797, 298
(1
), pp. 356
–362
.11.
Lin
, C. T.
, and Lin
, K. L.
, 2003, “Contact Angle of 63Sn-37Pb and Pb Free Solder on Cu Plating
,” Appl. Surf. Sci.
0169-4332, 214
, pp. 243
–258
.12.
Yost
, F. G.
, Michael
, J. R.
, and Eisenmann
, E. T.
, 1995, “Extensive Wetting Due to Roughness
,” Acta Mater.
1359-6454, 43
(1
), pp. 299
–305
.13.
Abtew
, M.
, and Selvaduray
, G.
, 2000, “Lead-Free Solders in Micro Electronics
,” Mater. Sci. Eng. R.
0927-796X, 27
, pp. 95
–141
.14.
Prabhu
, K. N.
, Fernandes
, P.
, and Kumar
, G.
, 2009, “Effect of Surface Roughness on Wetting Behaviour of Vegetable Oils
,” Mater. Des.
0264-1275, 30
(2
), pp. 297
–305
.15.
Lavi
, B.
, and Marmur
, A.
, 2004, “Exponential Power Law: Partial Wetting Kinetics and Dynamic Contact Angles
,” Colloids Surf., A
0927-7757, 250
, pp. 409
–414
.16.
Yang
, S. -C.
, Ho
, C. -E.
, Chang
, C. -W.
, and Kao
, R. C.
, 2007, “Effect of Zn Addition on the Interfacial Reactions Between Cu and Lead-Free Solders
,” Materials Research Society Symposium, Proceedings 968
, V. P.
Atluri
, S.
Sharan
, C. -P.
Wong
, and D.
Frear
, eds., Warrendale, PA, Paper No. 0968-V03-03.17.
Prabhu
, K. N.
, and Fernandes
, P.
, 2007, “Determination of Wetting Behaviour, Spread Activation Energy and Quench Severity of Vegetable Oils
,” Metall. Mater. Trans. B
1073-5615, 38
(4
), pp. 631
–640
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