Intermetallics formation between metallization conductor Pd-Ag and solder 62Sn-36Pb-2Ag have been investigated by transmission electron microscopy (TEM) and X-Ray diffraction. Energy-dispersive X-Ray (EDX) analysis and Selected Area Electron Diffraction (SAED) analysis reveals the formation of the intermetallic compounds Ag5Sn,Ag3Sn,Pd2Sn,PdSn2,PdSn4, and PbPd3. X-Ray diffraction results confirm the coexistence of the above metallurgical phases and additional intermetallic compounds including Pd3Sn2, PdSn, and Pb3Pd5. Evident single phase intermetallic compound (IMC) layer structure is not observed. The different intermetallic phases coexist near the metallization/solder interface. Silver-tin intermetallic compounds are also observed in the solder.

1.
Wang
,
Sea Fue
,
Dougherty
,
Joseph P.
,
Huebner
,
Wayne
, and
Pepin
,
John G.
,
1994
, “
Silver-Palladium Thick-Film Conductors
,”
J. Am. Chem. Soc.
,
77
(
12
), pp.
3051
72
.
2.
Klein
,
J.
and
Wassink
,
R. J.
,
1987
, “
Notes on the Effects of Metallisation of Leadless Components on Soldering
,”
Hybrid Circuits
,
13
, pp.
9
12
.
3.
Chiou
,
Bi-Shiou
,
Liu
,
K. C.
,
Duh
,
Jenq-Gong
, and
Palanisamy
,
P. Samy
,
1991
, “
Temperature Cycling Effects Between Sn/Pb Solder and Thick Film Pd/Ag/ Conductor Metallization
,”
IEEE Trans. on CHMT
,
14
(
1
), pp.
233
237
.
4.
Shangguan
,
D.
,
Achari
,
A.
, and
Green
,
W.
,
1994
, “
Application of Lead-Free Eutectic SnAg Solder in No-Clean Thick Film Electronic Modules
,”
IEEE Transactions on CPMT Part B-Advanced Packaging
,
17
(
4
), pp.
603
611
.
5.
Li
,
G. Y.
, and
Chan
,
Y. C.
,
1998
, “
Aging Effects on Shear Fatigue Life and Shear Strength of Soldered Thick Film Joints
,”
IEEE Trans. on CPMT Part B-Advanced Packaging
,
21
(
4
), pp.
398
406
.
6.
Lau, John H., 1991, Solder Joint Reliability-Theory and Application, Van Nostrand Reinhold New York.
7.
Marshall, James L., Foster, L. Ann, and Sees, Jennifer A., 1994, Interface and Intermetallics, Van Nostrand Reinhold, New York, p. 42.
8.
Li
,
G. Y.
, and
Chan
,
Y. C.
,
1999
, “
Diffusion and Intermetallics Formation between Pd/Ag Metallization and Sn/Pb/Ag Solder in Surface Mount Solder Joints
,”
Mater. Sci. Eng., B
, No.
2
, pp.
116
126
.
9.
Muckett
,
S. J.
,
Warwick
,
M. E.
, and
Davis
,
P. E.
,
1986
, “
Thermal Aging Effects Between Thick Film Metallizations and Reflowed Solder Creams
,”
Plat. Surf. Finish
,
73
(
1
), pp.
44
50
.
10.
Morrow, J. D., 1964, “Cyclic Plastic Strain Energy and Fatigue of Metals,” ASTM STP 378, ASTM, Philadelphia, PA, pp. 45–78.
11.
Brandes, E. A., and Brook, G. B., 1992, Smithells Metals Reference Book, Butterworth Heinemann Ltd.
12.
Wassink, R., and Klein, J., 1989, Soldering in Electronics, Electrochemical Publications Limited, England.
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